The value of all farms, hunting land and other rural land and acreage for sale in Pepin County recently was approximately $9 million, representing a total of 695 acres of land for sale in Pepin County. Pepin County ranks 70th out of 72 counties in the state for the combined amount of land currently advertised for sale. Of all locations in Pepin County with farms and rural real estate for sale, Arkansaw had the most land for sale. Pepin County is Wisconsin's 72nd largest county (248 square miles). It's located in the Northwest Wisconsin region of the state.